Try if you can to peel your eyes off of Leighton Meester’s gorgeous Nina Ricci Agneau Pleated Besace purse for one second, and take a gander at those killer heels (they’re part of the Chloe Sevigny/Bass collaboration for Opening Ceremony, by the way). Leighton, seen her with co-star Kelly Rutherford, looks a far cry from prep debutante Blair Waldorf in her edgy ensemble, but the girl does have a knack for finding hot designer pieces – on set or off.

Photo from PopSugar.com.